N，N＇-双(3-羧基水杨醛叉缩胺乙基)草酰胺均双核铜(Ⅱ)，镍(Ⅱ)配合物合成和性能研究

The homobinuclear complexes of Cu (Ⅱ) and Ni (Ⅱ) with N, N＇-bis(3-Carboxyl salicyl aminal ethylene) oxalamide were synthesized, and characterized by elemental analysis, IR spectra, Uv-visible spectra, conductometry, thermogravimetry, and magnetic susceptibility measurement, which indicated the complexes own an oxalic amide bridge-linking structure. Room temperature magnetic moment data show that there are antiferromagnetic spin coupling through oxalic amide conjugated double bond, In DMF, the redox half wave potential of Cu (Ⅱ) binuclear complexes have been measured by cyclic voltammetry, which proves that the Cu (Ⅱ) complex has two redox waves.     

N,N′- 双(3-羧基水杨醛叉缩胺乙基)草酰胺均双核铜(Ⅱ),镍(Ⅱ)配合物合成和性能研究

近来发现草酰胺具有多原子成桥功能,Kahn和廖代正等人^[1,2]设计合成一些对称和不对称草酰桥联的双核及多核配合物,并对其性质进行研究,本文报导N,N'-双（3－羧基水杨醛叉缩胺乙基）草酰胺配体及其铜（II）,镍（II）均双核配合物的合成和表征,及铜双核配合物的电化学性能研究。     

Determination of water states and the structural parameters of W/O microemulsions

The states of water in sodium bis(2-ethylhexyl) sulfosuccinate (AOT)/isooctane/water reverse(W/O) microemulsions system have been investigated by using Fourier transform infrared spectroscopy(FT-IR) technique. The broad peak obtained for hydroxy(O-H) of water has been resolved by least square curve-fitting. It has been observed that the water solubilized in microemul-sion droplets has four states, i.e. bound water with sulfo-group, free water, bound water with sodium counterion in the water pool of microemulsion droplets and a small amount of trapped water in the palisade layer of microemulsion droplets. The following have also been determined: the aggregation number (n), the radius of the water pool in the microemulsions(rw), the thickness of the bound water with sulfo-group(d1), the thickness of the bound water with sodium counterion(d2), the total thickness of the bound water (d) and the effective area of head groups of AOT(AAOT).     

Obtain Lower-Dimensional Turbulence Systems from Higher-Dimensional Lax Integrable Models

Taking the well known (1- l)-dimensional turbulence system,the Korteweg de-Vries Burgers equation,as a special example,we show that some types of lower-dimensional turbulence systems may be derived from some higherdimensional Lax integrable models,say,the (2 1)-dimensional asymmetric Nizhnik-Novikov-Veselov equation.On the other hand,using the Lax pair of the original higher-dimensional integrable model(s),we may obtain higher-dimensional Lax pair(s) for a lower-dimensional turbulence system.``     

表面活性剂和四烷基溴化铵的复配 Ⅲ.四烷基溴化铵碳氢链长对离子型表面活性剂在气/液表面吸附行为的影响

本文考察了四烷基澳化铵(TAAB)碳氢链长对离子型表面活性剂SDS和DTAB在气/液表面吸附行为的影响.实验结果表明,与表面活性剂离子对应的添加剂反离子是影响其水溶液表面活性的主要因素,因而TAAB对SDS表现出明显的效应,对DTAB影响效果则和同浓度的NaBr类似.除了对表面活性离子头基电荷的静电屏蔽外,TAA+的碳氢基团和SD-碳氢链间还可能发生疏水相互作用,但后者受TAA+离子体积制约.TAAB对SDS在气/液表面吸附行为的影响是上述几个因素的综合作用结果.     

铝对人类智能的损害及其对策的研究

论述了铝对人类智能的影响。铝的来源主要包括环境铝,食物性铝,炊具中的铝和药源性铝。铝对人类智能危害的基本原理是铝可进入大脑,与脑神经结合形成脑组织神经原纤维缠结和老年斑。防治的方法是减少污染,及时应用铝络合剂排出体内的铝。     

考虑边流量有限的网络路径博弈问题研究

考虑每条边有流量约束的网络路径博弈问题, 根据收益函数单调递增的特点分析其内在零和性质, 并建模为存在公共边的路径博弈模型。在寻找均衡解的过程中, 首先考虑非合作的情形, 在局中人风险中性的假设下, 给出了求Nash均衡流量分配的标号法并证明该均衡分配的唯一性。接着进一步考虑局中人合作的可能性, 给出模型求得所有局中人的整体最大收益, 并基于纳什谈判模型给出目标函数为凸函数的数学模型确定唯一收益分配方案。事实上, 该方案是对剩余价值的平均分配。最后给出一个算例, 验证本文理论和方法的可行性。关键词:流量约束; 均衡流量; 网络路径博弈; 收益分配     

连续区间策略下二人零和对策问题研究

考虑连续区间策略下的二人零和对策问题,研究其均衡策略的存在性。首先分析了完全信息下的二人零和对策问题,证明了该问题均衡策略的存在性并给出求解方法。然后进一步研究了收益函数不确定的不完全信息二人零和对策问题,在各局中人都认为对方是风险厌恶型的假设下,分析该类对策纯策略均衡的存在性,并通过研究纯策略均衡存在的充要条件给出判断并寻找纯策略均衡解的方法。最后给出一个数值算例,验证本文所提出方法的可行性。     

一类中值定理双介值问题命题的注记

在中值定理类双介值问题的命题中,很多命题者没有注意到结论的平凡性.文章借助于微分Darboux定理,证明了对应的非平凡问题解的存在性.     

一类自相似集重分形分支的量纲

本文首先定义具有量纲函数的重分形测度,然后证明当Euclid空间中的两个重分形测度具有等价的量纲函数时,它们也等价.进一步,对于直线上满足强分离条件(SSC)的自相似集,在某些加倍条件下,本文给出判断其重分形分支的量纲函数的充要条件.